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1 article(s) from Tron, Gian Cesare

Icilio Guareschi and his amazing “1897 reaction”

Gian Cesare Tron,
Alberto Minassi,
Giovanni Sorba,
Mara Fausone and
Giovanni Appendino

Beilstein J. Org. Chem. 2021, 17, 1335–1351, doi:10.3762/bjoc.17.93

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Graphical Abstract

Figure 1: Icilio Guareschi (1847–1918). (Source: Annali della Reale Accademia di Agricoltura di Torino 1919, ...

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Scheme 1: Vitamin B₆ (pyridoxine, 1), gabapentin (2), and thymol (3).

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Figure 2: Baliatico (Nursing) by Francesco Scaramuzza (275 cm × 214 cm, Parma, Complesso Museale della Pilott...

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Figure 3: Schiff’s fictitious report on the foundation of the Gazzetta Chimica Italiana (Image reproduced fro...

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Scheme 2: Reaction of thymol (3) with chloroform under the basic conditions of the Guareschi–Lustgarten react...

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Figure 4: The chemistry building of Turin University in a historical picture. Note, that one of the “mysterio...

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Scheme 3: Triacetonamine (6) and the related compounds phorone (7), α-eucaine (8), and tropinone (9).

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Scheme 4: Taxonomy of the Guareschi pyridone syntheses.

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Scheme 5: The catalytic cycle of the “1897 reaction”.

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Scheme 6: Resonance forms of the radical 10.

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Figure 5: The wet chamber used by Guareschi to restore parchments (Gorrini, G. L'incendio della R. Biblioteca...

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Figure 6: The Guareschi mask. (Servizio Chimico Militare. L'opera di Icilio Guareschi precursore della masche...

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Figure 7: Guareschi’s bust at the Dipartimento di Scienza e Tecnologia del Farmaco of Turin University. Permi...

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Published 25 May 2021

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